seeds Chenzo pepper & seeds ?

Here is a photo of a couple of my Chenzo peppers.
I did not get a bountiful crop from the one plant I grew this year.
Only about a dozen pods and many of them are just starting to turn black.
They will, if given time and the right conditions turn red.
My question is:  Would the seeds be viable at this stage (black) or is it best to collect seeds after they are fully ripened to red?
 
Chenzo_zpsf7ufcexy.jpg
 
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