As far as better germination rates, I consider sterile/sanitary conditions and maintaining proper heat and moisture levels as most significant. The responses above both focus on minimizing pathogens, which to me is what really matters with slower seeds. If a seed is fresh and strong, it's going to power through many pathogens and tend to germinate quickly and without issue. Older, weaker seed may be viable, but grow more slowly, allowing pathogens time to proliferate, which means a seed that might otherwise survive may succumb prior to breaking the surface. I think a lot of seed failure is due to this.
It would be cool to see what affect willow water had on germination and early growth. It wouldn't be hard to soak a seed in it and see what happened. Just maybe not a rare "last seed" of some fancy variety