chilehunter-
I'd recommend following the Kerr or Ball canning guides for fruits and vegetables. Get or look up a good canning guide, don't follow the "i've done it this way for years and never had a problem" ideas posted on forums.
Peppers/chiles are considered a low acid vegetable and should be pressure cooker canned. Fruits can usually be hot water bathed especially if it's a fruit in a sugar-water syrup.
Many years ago we did about 20 quarts of homegrown green beans with a hot water bath. Stuck them in the pantry, and about 6 weeks later, they started to "explode"...not literally.... but foaming and leaking all over.... they should have been pressure cooked, not hot water bathed. If we'd eaten one of those jars, we'd have been in a whole other world of hurt!
Green beans, vegetables in general, and most modern tomatoes have "low acid" and must be pressure canned. You can add acid such as vinegar to green beans, and then you are getting into the pickled category.......
Most university extension services, who offer help for home canners, say to pressure can tomatoes, even though traditional canning methods will say to use the hot water bath method. That is because modern growers have been breeding the tomatoes to reduce the natural acid that used to be present in the the tomatoes to have "low acid" tomatoes of today. So that is why they are now saying to pressure can tomatoes when they used to not say that. Heirloom tomatoes may still have the higher acid content, but do you want to risk it?
One other note-
for home-canned vegetables, make sure the veggies are BOILED for 10 minutes before eating to "kill tall the nasties". Don't just heat the home canned veggie in the micro.
Pressure canners are not to be feared. Respected and appreciated, but not feared~~~