Wild fluctuations in moisture availability is usually the culprit (too little followed by too much). If nothing has changed as you say than I can only speculate perhaps the moisture levels are too low for the size of your plants which is why your seeing it at the end of the season as the plants reach full size and heavy fruiting. You could either increase their water regime or prune the plant back to see if it helps. Calcium could be the cause but it seems unlikely. A plant actually uses very small quantities of soil bound nutrients, it synthesis the bulk of its make up from water and sunlight. I dont understand how you killed oregano with mulch unless you buried the plant but even then oregano is pretty tenacious. Mulch is the number one thing you can do to improve any growing situation. It releases water when the soil is too dry and wicks it away when soil is too wet. It improves soil nutrition and tilth through decomposition, increases biological activity in soil by provideing habitat, reduces weeds and the spread of soil borne pathogens and fosters growth of the most important player of all mycorrhizae fungus. The soil is alive. Any organism needs a protective skin and mulch is just that.
I actually just did alittle further research into the problem and found this
http://ucanr.edu/sites/placernevadasmallfarms/files/86509.pdf. Apparently calcium moves through the plant through transpiration. Water transpires from leaves much faster than the fruits therefore the calcium ends up there. Seems like again the problem is caused by removing the plant from its naturally slightly shady enviroment (30% shade showed an increase in pepper production in a university of georgia study). This also explains why larger thick walled peppers are more likely to suffer from BER. I never see BER or almost any problems in small peppers like birds eye or thai or even cayenne. Now keep in mind that BER looks almost identical in tomatos and peppers, the end turns brown black and sunken. If your chillies are fine outside but black brown and moldy inside this is not BER, it's a fungus that forms on the flower itself which is how it ends up inside the pod. The only way i know how to prevent this is with a fungicide application prior to fruiting which i do not do nor condone, one for my own personal safety and two because of the threat it poses to pollinators.