I'm not talking about live pods on the plant. Peppers are traditionally dried in the Southwest strung up in ristras which are hung out in the open air. In a natural environment they dry up on the plant and fall on the surface of the ground and are exposed to the same temperatures, still producing viable seed.
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Apparently (courtesy of google) there is an equation for seed viability that depends on time, temperature, moisture content, and several species specific constants. Source:Â
http://hortsci.ashspublications.org/content/44/6/1679.full
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where
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p : time in days
t : temperature in Celsius
m: moisture % of fresh weight
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"universal" values for CH and CQ and species specific values for KE and CW
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So now we can calculate it (yay!). This explains how seeds remain viable in hot desert environments: the moisture level is low which is good for seed life. What I still don't know is what temperature is lethal to chili pepper seeds in the short exposure times typical of the pepper drying process. The temperature to kill varies significantly by species, take a look at the chart on page 2 here:Â
http://aggie-horticulture.tamu.edu/vegetable/files/2010/10/E-326.-Easy-Gardening-Composting-to-Kill-Weed-Seeds.pdf Some species are dead in a matter of hours at 108F, others can handle 115F indefinitely and some can survive for several days at 122F.