I have a background in mathematics, not chemistry - so I'm not sure if my explanations will do much to satisfy your query. Let's go...
SuburbanFowl said:
Focusing on electrical charge, hypothetically, does it matter what kind of ++ ions we are buffering with? (I'm talking purely in the sense of exchanging the sodium and potassium ions)
Sure it does. Because the type of ions that we put in, are a function of what we are starting with, and what we want to end up with. We know the physical makeup of the coco, so it has this very specific set or requirements. I suppose it's a bit of a natural coincidence that it has the requirements that it does.
I don't know off the top of my head every double positive charged ion. But I suppose if you wanted to exchange some iosotope for Ca, you probably could. After all, the Bikini Atoll coconuts thought Cesium was Potassium, right?
SuburbanFowl said:
Based on phrases you used above, I am confused ("displaced" with regards to sodium vs "freed up" with regards to potassium). Are you saying that, to the best of your knowledge, even fully "pre-charging" coco will not result in all of the K+ being exchanged?
That is correct. In fact, if the CEC is not fully satisfied, it will even start to grab onto Na+ and K+. On the other hand, when it is met, it will give off Na+ and K+. Which is exactly why you want to make sure that you have that out of the way before plant out. K+ is less worrisome than Na+, obviously. but it's still a function of your TDS/EC, and should therefore, be considered important. As much as this seems like a masturbatory exercise, anyone growing in coco should be giving the pre-charging, buffering, whatever you want to call it, a significant amount of attention, if best results are desired. And, for all the talk about it, it's really not a difficult thing to achieve. We've just made it sound far too academic.
SuburbanFowl said:
Why would Na+ be "displaced" and yet K+ be "freed up"? Are you using the terms "displaced" and "freed up" to simplify the explanation, or are these terms being used mutually exclusively?
Is the use of "displaced and "freed up" because the ratio of K:Na in the colloids (in "un-buffered" coco) is different, generally speaking? (Higher ratio of K:Na in "un-buffered" coco, on average)
The choice of words - "freed up" and "displaced", effectively mean the same thing. You're using the double positively charged ions to push out the single positive charges. We are simply attempting to reach the CEC (cation exchange capacity) and be done with media buffering. That way, all nutrients that we add to the plant later on, are 100% (theoretically) available to the plant, and not being absorbed by the media.
SuburbanFowl said:
Are you saying that Na+ specifically will be exchanged for Ca++?
Wouldn't the same be true for K+ being exchanged with Ca++? (You specifically mentioned Calcium being used as the buffer in your previous post)
Specifically? No, probably not. This is a re-phrasing of your previous question. ++ pushes out +. I can't answer the specifics about how the CEC equilibrium is reached. But there is clearly such a thing. Else, buffering would never be achieved.
SuburbanFowl said:
Assuming this is true, what is the difference between K+ and Na+ here? If we flush it properly with Calcium Nitrate (which would contain NH4+ and NO3+ but lets ignore that) and equilibrium has been reached then shouldn't all of the possible sites (that can be exchanged) containing Na+ and K+ have been exchanged for Ca++?
Once equilibrium has been reached, there will still be Na+ and K+ present, presumably (Am I correct)?
Have I got this right and our goal with "pre-buffering" is to get the media to have a completely (as much as possible) fulfilled CEC?
You can ignore the component molecules of NH4 and NO3, for the same reason that you can ignore the single positive charged molecules in the coco coir. The double charged ions are the ones that are doing the work. (attaching more readily, and displacing other single charged molecules, up to some point)
Again, yes, there will still be SOME K and Na present. But the problem that you had before, when you weren't buffered - and even worse, when unwashed - is that you were progressively buffering and/or leeching, thereby having all of your Ca absorbed into the media, and letting out too much Na and K to be useful (or even harmful). That could be possibly creating antagonistic relationships, or a completely unbalanced nutrient load.
When the CEC is achieved, your nutrient is feeding the plant, not the media.