Reading replies, I am thinking that for powders the investment would be mainly to please the health official. He seemed to really dig on the idea.
Neoguy, freeze drying freezes the pods very fast and very cold, thus preserving texture and some nutrients / flavor that might otherwise be lost. Then a vacuum is applied as they are warmed, drawing off the moisture as they do. Not sure about the nutritional value, but vegitables that were freeze dried have more of the original shape and texture than those that were dehydrated. Not saying they look fresh, but a whole lot better than they look dehydrated. No clue why a person would freeze after dehydrating other than extending life. But freezing fresh pods before you dehydrate is recommended by my health official because it destroys more bacteria than simply dehydrating.
Robby, I am just now getting my ducks in a row for being able to make powders. Canning is a whole other can of worms. I do it for myself, water bath and pressure, but the regulations for canned goods are many. Rightfully so. My wife met someone in a cooking forum who killed a church member and made many, many others sick. Give it a google: I think it was botulism from canned potato. Scary stuff that is.
Moruga, I do not know for sure but I believe freeze drying makes for a better looking product. More vibrant color without preservatives. I know it preserves the texture better but being we are talking hot peppers, I dont think that matters as they are usually ground up before cooking. Now sweet bell peppers, oh my the freeze dried ones I have bought are so much better than dehydrated. Put them in a chili or stew. In your mouth the freeze dried ones feel more like fresh.
I asked because looking into powder making and the health official suggested freeze drying as one possible process for powders. He seemed to really push freezing first and I get the feeling he thought of freeze drying as an automated way of doing that. He did not stress the lower than normal freezing temperatures or being able to extract more moisture. I get the feeling he has a lot of experience with deer jerky.