Insecticidal soap treatment and yellowing leaves: Mg deficiency? Epsom salt?

Hi all, old reader but new user here!
 
So this year has been our first try at growing some peppers (and some bell peppers): padrón peppers, purple cayenne, thai super chili F1, ghost pepper and some unknowns. We now have fast interveinal chlorosis and a thrips problem.
 
Some background (might or might not be relevant):
 
We started under grow lights inside (proper custom IKEA cupboard build) during winter season (summer is short in Sweden) and moved out when we got decently long periods over >10°C. They are located in large balcony boxes with soil meant for roses (recommended by Swedish chili grower; not quite as acidic as most Swedish peat-based soil types) mixed with ~10-12 % vermiculite (retain some nutrition and minute water) and ~18-20 % perlite (improve airing and draining). All soil is completely covered by a thin layer white plant-ornamental stones (pretty, holds down perlite from floating up when watering, and gives some nice sun light reflection). They've been fed with Chili Focus (3:1:4.4 NPK plus all micro/traces, even inc. 1.57 % w/v Ca) and foliar feeded with epsom salt once before (~1 % v/v + dish soap, 6-8 weeks ago maybe).
 
When they were young we had many problems with thrips as well as all new leaves becoming deformed (possibly thrips and/or Ca deficiency due to worse, peat based soil). We treated this with frequent application of organic pine based soap (soap is a salt of potassium, not sodium) at 1-2 % v/v and once or twice with horticultural (light, summer) oil and this new nutrition. The oil they didn't like but recovered. The soap has never been a noticable issue before and killed of the thrips quite efficiently. They got very stunned by the thrips (and possibly the oil), delayed a couple of weeks/months but finally grew and are now outside.
 
The problem (soap treatment and yellowing leaves):
 
We got the thrips back. They had managed to do some unfortunate damage before proper detection and a soaping was in order (first one in 3 months or so). Usual 1 % v/v soap was applied 3 days ago and some unfortunately got in soil (more difficult to avoid when they're large and in huge boxes!), but we tried to be careful. No wash-off. Yesterday we noticed some fast yellowing of the older leaves, it looks vaguely like interveinal chlorosis (veins are more green but not really "strikingly green") with some fall-off. We've had gradual yellowing and fall-off of older leaves before but not really cared too much since young leaves has been fine and blossoming+fruit has occurred multiple times. Stems are now however getting very naked on the lower part.
 
So we all know interveinal chlorosis, and particularly a pattern spreading from the oldest leaves and upwards is a (possible) sign of magnesium deficiency. Furthermore I found this guide (haifa-group.com), which I quote on Mg deficiency (my emphasis):
Is Common on pepper plants. Yellowing of the leaves is apparent in the interveinal areas and veins remain green. The oldest leaves are affected first. Sometimes magnesium deficiency occurs when excessive applications of potassium have been made. It may also show up under extremely hot dry weather.
 
This combined with the soaping (which definitely contains potassium) seems like a likely culprit, or is it far-fetched of me? Furthermore the nutrition, "Chili Focus", doesn't mention how much Mg it contains; Likely because it's only in the minute amounts that are actually necessary (being a micronutrient and all). Since soaping will lead to foliar absorption of potassium (focusing the problem at the problem site?) and some even went in the soil, I'm seeing a possible problem of Mg lockout here. Oh, and Swedish hot weather is... not extreme.
 
Current action (epsom salt foliar application + more light hours):
 
Yesterday we sprayed all leaves with ~0.8 % v/v epsom salt solution (~½ tablespoon/quart), which is pure MgSO4 for those who've not heard of it, and a very minute drop of dish soap (as wetting agent) to try to counter this wild hypothesis via a mega-dose of Mg (it really is a mega-dose when you spray epsom salt considering how little magnesium is needed) to the problem area, and put the worst victims (bhut jolokia) on full light treatment (safe and cozy grow light during night, Swedish summer during day).
 
Some questions:
  1. Is it likely we're having an acute Mg deficiency caused by (potassium salted) soap treatment?
  2. Can we combine epsom salt directly in the soap solution (maybe at half concentration, 0.5 v/v %) for next soaping to counter act the lockout to begin with? Some thrips are alive so we really need to soap again soon.
  3. Have we missed something? How could we exclude other problems?
  4. What else can we do?
We really don't want to see our bhut jolokia go (most serious victims seem to be them), they're so close to giving us mature fruits but have lost so many old leaves now! We would be extremely grateful for help and advice from wiser members here. We're first-time growers and know nothing except what we've been forced to learn as of yet, mostly the hard way.
 
Please send help.
 
I made a gallery of some pictures on plants displaying the issue. I'm also including direct links here (don't know if they'll show up):
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TakashiLM said:
at first, looking at the pictures only, is it possible that you overwatered these plants?
It's certainly not impossible. We've struggled a bit with finding a good balance of watering. Our plants had a tendency to wilt quite quickly whenever the earth dried up completely (likely because of relatively small volume of earth) and a day passes (i.e. the horror when you come home after work); This has not happened for a few months however. We've tried to be more careful recently with overwatering but I'll keep this in mind moving forward.
 
Is there something in particular in the images that make you think they're overwatered? If you google it the signs seem to be a wilted look with rolled up leaves, which is not really something I'm seeing.
 
Oh, and thank you so much for the input!
 
SwedishGhost said:
It's certainly not impossible. We've struggled a bit with finding a good balance of watering. Our plants had a tendency to wilt quite quickly whenever the earth dried up completely (likely because of relatively small volume of earth) and a day passes (i.e. the horror when you come home after work); This has not happened for a few months however. We've tried to be more careful recently with overwatering but I'll keep this in mind moving forward.
 
Is there something in particular in the images that make you think they're overwatered? If you google it the signs seem to be a wilted look with rolled up leaves, which is not really something I'm seeing.
 
Oh, and thank you so much for the input!
 
Yeah, some time ago I had 1 week straight of non-stop rain and by the end of it, some of the leaves looked just like those yellow ones in the pictures... I didn't have much knowledge about nutrients deficiency back then, so what I did was remove 1-2 inch of soil around the plant and I filled in with worm casting. It took some time to recover but it did.
However, I'm still not capable to say if that's magnesium deficiency or anything, I'm sorry.
 
TakashiLM said:
 
Yeah, some time ago I had 1 week straight of non-stop rain and by the end of it, some of the leaves looked just like those yellow ones in the pictures... I didn't have much knowledge about nutrients deficiency back then, so what I did was remove 1-2 inch of soil around the plant and I filled in with worm casting. It took some time to recover but it did.
However, I'm still not capable to say if that's magnesium deficiency or anything, I'm sorry.
 
Thank you sharing!
 
Unfortunately I did water them all with the "Chili Focus" feeder about an hour before your first post since some seemed a bit droopy and I got paranoid of adding the stress of drought to their current condition. I'll just make sure to let the soil dry out thoroughly, and try to let each of them wilt at least just a little, before the next watering. Going to watch the weather report for rain as well.
 
Still remaining a bit sceptical since they do not seem to have "wet wilt" or feel very water soaked. Some leaves are quite light green though. Hmm. It's so strange.
 
Do you (or someone else) have any idea if it's fine adding epsom salt to a soap solution? I don't want to go many more days leaving the thrips to thrive before they get nuked with soapy water again, and I'm feeling a bit wary of not doing anything to counter my wild potassium-antagonistic hypothesis.
 
Update: A lesson learned
 
Conclusion: You can absolutely not mix epsom salt with your insecticidal soap. Do not attempt it!
 
Explanation: Soaps and detergents are less effective in hard water. This can e.g. affect your clothes washing where you might need a special product that works (better) in hard water. The reason is that the soap salts will precipitate to non-soluble compounds in the presence of Ca2+ and Mg2+ ions, which is what defines hard water. Are you starting to see the problem?
 
We call water hard when it's above 3°dH (German degrees) and very hard above 10°dH, or so. A solution of epsom salt in e.g. 0.4 v/v % will effectively be very hard water. How hard? Well anhydrous MgSO4 (epsom salt) has a molecular weight of 120.366 g/mol. This makes a 0.4 v/v % solution of MgSO4 contain about 0,0332 mol/l or 33.2 mM Mg2+ ions. According to an internet search this would constitute ~185°dH. Extremely hard water, that is.
 
Effectively all your soap will precipitate as non-soluble salts. You pretty much ruin both the insecticidal property of the soap and the fertilizer property of the epsom salt. So don't do it.
 
The correct way: Soap first, let it dry fully, spray with water and then spray epsom salt. Soap is only effective when wet so we can clean it away when it has dried. In this manner the soap will never get ruined by the epsom salt (which we can't wash off immediately since we want it absorbed).
 
What I did: Exactly what made me write up this post so no one ever attempts it again. I only noticed the problem after soaping (drop some soap into your epsom solution and it will become quite apparent) so now I just hope that I haven't damaged the plants by these non-soluble magnesium salts (and that the soaping has at least had a very minute effect).
 
Dont worry about it. the new growth looks ok and that's all that really matters.
Old leaves degrade, get damaged and die to make way and allow light to reach new growth.
Just pluck off the old leaves that look less than perfect.
If it were the new growth discoloring that would be an issue, but its not.
you are fine 
 
nzchili said:
Dont worry about it. the new growth looks ok and that's all that really matters.
Old leaves degrade, get damaged and die to make way and allow light to reach new growth.
Just pluck off the old leaves that look less than perfect.
If it were the new growth discoloring that would be an issue, but its not.
you are fine 
Thank you nzchili. It is indeed comforting that new growth is good. I do still suspect that most people with such naked stems would be a bit worried! If nothing else it means there's a lot of photosynthesis that the plant misses out on via the light just hitting the wall behind it.
 
In the spirit of update I can add the most likely culprit:
 
The tap water is terrible with pH 8.4 and alkalinity 1.52 mEq/l. I suspect a gradual build up in the pots over many months of watering (lack of run off should make it worse due to lime scale buildup). The soil now most likely has a bad pH for nutrient absorption (particularly iron, but also phosphorous and nitrogen). The soap has a pH of 10 (maybe 9 or so when in solution), neatly explaining why the problem gets worse after a soap treatment (a fair amount goes into the soil). The fertilizer is buffered and so enables temporary utilization of nutrients (explaining why it seems to have worked for a day or two before); The bulk of the nutrients in the soil now are likely not available.
 
Current course of action:
 
Citric acid deep watering. My water would warrant about 0.1 g/L citric acid in all the irrigation water to counteract the alkalinity according to some recommendations from NC state university. I'm now using 0.5 g/L in the hope of also coping with previous build up. 4 days after first pH adjustment, the leaves (especially the younger ones) are noticeable more dark green and all leaves are thicker (they feel like leaves and not almost like toilet paper)! Several plants have lots of thriving buds on the stems now. It's really feels like the pH alone have made a lot of already present nutrients available to the plants.
 
I don't know if my updates are of interest but I do hope that someone who googles their way here in the future will be able to learn something from on my troubleshooting.
 
Good read!
 
I'm very interested in the soap solution for the thrips, as I live in Norway where you need to be a registered farmer or similar to buy pretty much any kind of pesticide. Neem oil is classified as a medicine and is of course also not available without a prescription  :rolleyes:
 
I'm guessing I can get pretty much the same kind of pine based soap here as in Sweden though. 
 
I'm just curious if you always have used the method of letting the soap dry before you spray with pure water after? I was under the impression that the soapy water shouldn't be able to dry on the plant.
 
Edit: Oh, I just noticed this was from Juli 2017, and not 2018  :confused:
 
 
 
hmmm...  make sure you use insecticidal soap correctly.    in order to be effective, soap must come into contact with the pest.   don't spray whole plant.   just spray the infected area.    even though it's insecticidal soap, it can  harm your plant.  anyway i prefer other method to detroy pest.
 
as for watering, i think you worry too much. 
let me show you my past experiment with pepper plant, i only water when my pepper look like this
 
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it will bounce back within an hour.
 
 
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