Sorry to resurrect this old thread, but I felt the need to add to the data here. This seems to be a common thing with fluoro lighting, because my Jalaps are also getting purple color to their leaves under a T5 Quantum Badboy. What's interesting to me is that the bulbs I have in the system are from a company on eBay and are not the standard bulbs that Quantum makes.
Quantum makes what they call "TRI-phosphor" coated T5 bulbs. If what the previous poster said is true about the mercury emmiting UV light and the phosphor converting it to visible spectrum light, then it is possible that higher quality bulbs like those made by Quantum may prevent the tanning of pepper leaves, in theory. Anyone here use the Quantum T5 and their Tri-phosphor bulbs?
Pretty neat hypothesis going on here.