Im glad you are all right and that it doesnt seem to be powdery mildew, looks like i have to learn the hard way about how to sun harden , i even send some pics to the guys who make chilli focus and they to seem to think its sunburn. thanks for your comment patrick..The different angle in the second pic makes it look like sunburn to me now. Look at the edge of the leaf to the left and it's already beginning to darken. Won't be long and you'll be able to crumble it into ash. Yep, sunburn.