I hate all the misinformation and myths out there. Some people were adamant that a) seeds in nature don't freeze, and/or b) frozen seeds implode inside themselves, making them unable to germinate. Hogwash. And hogwash to that they had to be dried first. I had tossed some fresh pods into the freezer several months before and decided to take the seeds out of them and germinate them. I got 100% germination. In fact, I germinated way more plants than I wanted and I couldn't make myself throw any away, so I had a large amount of chile plants that year.
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THE ONLY THING that is key into whether the seeds will germinate for you (assuming you take the same care with your germination that you would take with any other seeds) is that the pods had to be ripe before you froze them or the seeds. Don't buy into frozen-seed myths that say they won't germinate.Â