miguelovic said:
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I had someone call me a liar when I said my ph meter didn't need adjusting after two years.
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i seem to recall a conversation somewhere along these lines. i think that was me. tho i do not recall calling you a liar. only that i doubted it was true.
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PH electrodes, are sort of like batteries. As the electrolyte flows out of the electrode, the reference electrode potential drops.
the theoretical
ideal ph electrode is 0mV at 7Ph, so as it ages, this value SHOULD remain constant regardless.
lower and higher than 7 however, will drift, as the internal reference potential drops.
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in the real world there is no such thing as an ideal ph electrode. IE 7 Ph is never 0.0 mV. there is also no such thing as a perfectly linear response, so calibrating with one solution is problematic unless you are measuring a solution at or very close to the calibrated value.Â
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most instruments do double and triple calibrations automatically, so i dont see the value in only doing a single point calibration, provided you have the extra 30 seconds of time. if you dont care about accuracy, then why use a ph electrode at all? get some paper.
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edit; with regard to instruments.
if its possible, i always reccoment a meter that will display the actual mV value along with the Ph. the mV is the basis by which your electrode is judged, with respect to its useful life. when a mV value at the 7.01 buffer drifts to substantially larger values, or when the drift accelerates, its time to get a new electrode.
Tank said:
You can get away without a means of testing PH (meter,strips or drops), at least until some issue pops up. My nute parameters never change but i still like to check every now and then just for peace of mind.
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Eh. i disagree with you here,mostly for one reason.
Ph paper is almost free. i know what you are saying tho.
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not everyone has the same tap water conditions. I have like 250ish mg/L carbonates in my water, it takes a mighty swig of HCl to drop it from like mid 7s to like lower 6ish.
some folks will have that angelic perfect crystal clear Scandinavian mountain glacier water. This water will require far far far less acid to drop the ph.
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in systems that recycle nutrients, ph and to a greater extent conductivity are of greater concern, as their values are indications of what is happening with the nutrient solution. too much ammonium, and Ph will drop, too little it will rise. etc etc.
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conductivity, same deal. dropping ec will indicate nutrients being consumed. conductivity that rises will tend to indicate excessive evaporation, as is the case with the bubble buckets, carrying away water vapor in drier environments, or excessivly high Ec to start with.