Yep, it's the flouros. When I upgraded from T12s to T5's mid-season this year, 80-90 % of my plants developed purple leaves (and still do - they don't quite get fully used to it), most developed dark purple stems, and about 30 % developed dark purple veins, exactly like your picture but more intense.
At first I thouht it would be a nitrogen deficiency, as that is the often-listed ailment for purple veins on pepper plants. But adding a high nitrogen fert did nothing, whereas taking some of the affected plants out from under the flouros and into the sun did resolve the issue within a few days.