Not sure. Here is something I found though.
Pepper - Capsicum annuum
PLANT: Most home gardeners will get satisfactory results if different varieties are separated by 50 feet and another tall, flowering crop. New studies from New Mexico State University show more crossing than was previously thought. We recommend at least 400 feet between varieties to ensure absolute purity.
FLOWER: Peppers produce perfect, mostly self-pollinating flowers. Solitary bees will pollinate if a more desirable pollen is not available in the area.
SELECTION TRAITS: Flavor: Hot, D
HARVEST: Harvest mature, fully-ripe peppers for seed. (Most bell peppers turn red when fully mature.) If frost threatens before peppers mature, pull entire plant and hang in cool, dry location until peppers mature.
PROCESS: There are two methods, dry and wet, to process pepper seeds. The dry method is adequate for small amounts. Cut the bottom off the fruit and carefully reach in to strip the seeds surrounding central cone. In many cases, seeds need no further cleaning. To process the seed from large amounts of peppers, cut off the tops just under the stem, fill a blender with peppers and water and carefully blend until good seeds are separated and sink to bottom. Pepper debris and immature seeds will float to the top where they can be rinsed away. Spread clean seeds on paper towel and dry in cool location until seed is dry enough to break when folded.