i would recommend waiting until after fermentation takes place to add any alcohol. i'm not 100% sure, but I suspect that alcohol would suppress lactobacillus activity; the reason I say this is that when there is alcohol to consume, you may inadvertently select for acetobacter, which will ferment alcohol into acetic acid, thus the vinegary taste someone else described. this also depends on whether or not the fermentation is exposed to oxygen, as acetobacter is an aerobic bacteria (needing oxygen), while lacto doesn't require it. regardless, i think for the process of fermentation to bring down pH for preservation, I would skip adding alcohol until the processing stage.