I would say it would depend on what you have going on and what you're using already. The best I could do is give you the info of how I use Cal Mag.
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For my hydro, I use 0.5 - 1tsp (2.5 - 5ml) per gallon of RO water each and every feeding (reverse osmosis water - meaning the water I use for my hydro starts around 0ppm, pretty much pure water before I add anything to it)
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For my soil, I use tap water because my soil has most everything it needs already, so I only supplement maybe every other feeding. My tap water runs around 300ppm. When I do add cal-mag to my soil feedings, I just add about 2ml per gal.
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Some people would say to add cal-mag every feeding no matter what. I feel that a little can go a long way, especially if using tap water. But some species require more (like the Carolina Reaper for example).
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If this makes sense to you, great! If not, then just know that most peppers tend to love cal-mag. Just add a little here and there and it shouldn't negatively effect your plants.