I'm not experienced enough yet to say that I'd be able to tell certain peppers apart. I'm hoping to be able to tell between the peppers I'm growing this year and then maybe I'll be able to expand on that next year.
I'm with ya on that Smokenstein. This is the first season I've actually been able to get past heat and really taste the fruitiness of different peppers. However, I can only really identify a few families of peps on taste alone.
I answered that I could tell the difference if there was a disparity in heat. If you gave me 10 varieties of superhots I surely would get confused on some of them. I know some tastes very well, because I am used to them. (ie orange hab, fatalii, caribbean red, etc.) However, if you gave me Bhut, Naga Morich, and Naga Jolokia back to back to back, I would never be able to tell. I will have to do further study on this though.
I imagine over time I could. Right now I'm too much of a noob.
@JayT I think you'd have to erase the sense of the last one to try the next. Kind of the way you cleanse your palate with pickled ginger when you have sushi. I bet if you spent a day getting to know those chili's you could do it.