That's a tough question. If you put them out too early, they can slump from the cool temps and become quite delayed as a result. This really happens and it can really screw over your season/production. Younger peppers and certain varieties are more susceptible to this than are peppers more established and/or more cool-comfortable.
For poblano and jalapenos - based on googling your monthly temps, I'd start hardening them off in April and I'd guestimate leaving them outside full time starting between maybe the third week in April and the first week of May, depending on the actually temperatures. That's a couple weeks earlier than what I do here, but your days seem notably warmer than ours during these months and your nights are a bit warmer too. Ideally, I'd aim for about 10c nights and 20c days, with hotter days making up a bit for slightly cooler nights. If you're transplanting to the ground versus containers, then soil temps will also figure into the equation.