I use similar analytical equipment in my PhD research, actually we have our own gas chromatograph in our lab. I'm thinking of buying some analytical standards for calibration and testing my own chillies in this way when it's not in use. I'm growing (amongst other things) the Carolina Reaper so It would be a good way to keep me entertained during my proper research work.
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For the record the presented procedure is not a new technique but actually the standard testing method. Only difference is she's using liquid chromatography not gas chromatography, accuracy is good for both techniques if performed properly.