Not to go against PHB and a lot of the growers that are here, but if you go through the pages you are going to inundated with people worrying about every wrinkle, spot, misshapen leaf, and the like. A lot of these questions are met with "Well, just add Cal-mag". This is the wrong answer. I would go as far as to say that among the top reasons people accidentally kill their plants is to overfeed and give the plant something that it doesnt need.
Growing peppers, and specifically supers, takes a bit of practice and I would STRONGLY recommend that you treat this year as a learning season. You will have problems, and now is the time to hone in your techniques. There are hundreds of growers here that can help you, but you also have to realize that patience is often the best practice. Ultimately, peppers need light, water, and some food. You do not need to feed them all the time, and depending on what you are using, you can go as little as a 2 or 3 times a season, or as much as every few waterings. For this first slew of plants, I would recommend trying a few things. If you want to go organic, stay away from the synthetics (cal-mag, pro-gro, most miracle grow) and instead chose fish ferts and tomato-tone like stuff.
What I really recommend is to start a GLog and that way you can have the community help you along the way. Post your questions, your concerns, and YOUR PICTURES, and that way we can help out and recommend minor tweaks along the way.
Lastly, as a testament to patience, last season I deployed half way through the season, at that point I just left my garden as is. My wife didnt feed it, water it, or do anything but weed it and PICK TONS OF PEPPERS. 3 months of letting mother nature handle the water, letting the soil take care of the food, and she pulled at least 20 gallons of peppers off in a 2 month period. (BTW, I told her not to worry about it and just harvest when she gets time, she offered to take care of it but I wanted to see how it would do if I didnt have a chance to kill it).
Good luck, and I look forward to watching your progress.
edit: this isnt ALWAYS the case, since having plants in containers may take a bit more management. But ultimately, less is more in the gardening world. Let nature do its thing and only intervene when it is absolutely necessary.